| 000 | 07319na a2201021 4500 | ||
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| 001 | 224068 | ||
| 003 | koha_MIRAKIL | ||
| 005 | 20221226090122.0 | ||
| 008 | 190118b tu 000 0 | ||
| 040 |
_aCY-NiCIU _btur _cCY-NiCIU _erda |
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| 041 | 0 | _aeng | |
| 090 |
_aYL 329 _b A96 2013 |
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| 100 | 1 | _aAwoh,Desire Kemena | |
| 245 | 0 |
_aRemoval of Bisphenol a from Aqueous solution using cone of Pinus Resinosa as a novel biosorbent _cDesire Kemena Awoh; Supervisor: Hatice Erkurt |
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| 260 |
_aNicosia _bCyprus International University _c2013 |
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| 300 |
_aXI, 65 p. _btable _c30.5 cm _eCD |
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| 336 |
_2rdacontent _atext _btxt |
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| 337 |
_2rdamedia _aunmediated _bn |
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| 338 |
_2rdacarrier _avolume _bnc |
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| 500 | _3Includes CD | ||
| 504 | _aIncludes references (57-64 p.) | ||
| 520 | _a'Abstract The use of biosorption technology in the removal of Endocrine Disruptive compound has being extensively studied and this work focuses on the use of cone of Pinus resinosa (as a adsorbent) for the removal of Bisphenol A (BPA) from a wastewater solution. Biosorption is the use of biological materials as sorbent using their physic-chemical pathways. This work investigates the removal of BPA under the following parameters, the effect of temperature, pH, initial BPA concentration, temperatures and biomass dosage. The maximun adsorption capacity of pine cone powder for BPA removal was (0.155 mg/g), the effective pH was 5.0. The percentage removal of pine was found to be at maximuim at 60 0C after 30mimutes and was (65.5 %). The study was carried out with different temperature ranges (40 0C, 50 0C, 60 0C), and different initial concentrations of 0.1ppm, 0.15ppm, 0.25ppm, and 0.5ppm. The biomass dosages are (0.3g, 0.2g, 0.1g and 0.05g). The result also shows that there was increase in the percentage removal as the biomasses increases but the sorption capacity was found to big high for 0.05g of pine cone powder. The Langmuir, Freundlich and Temkin isotherm models were calculated and the results fits well with the Temkin isotherm models for all three temperatures and it fits well for Freundlich isotherm models at 40 0C but did not fit the Langmuir isotherm models for all three temperatures. The R2 for Temkin isotherm models are (0.9233, 0.914, and 0.9833) for 40 0C, 50 0C, 60 0C, respectively. The results of the percentage biosorption removal were compared with the enzymatic removal with Laccase enzyme. The experiments was carried out with pH 4.0 C6H8O7 buffer solution and result for 4hours with 0.1ppm (23.66%) and 0.5ppm (24.38%) were compared with that of resinosa percentage removal. Keywords: Pine cone; Bisphenol A, Biosorption. Özet Endokrin bozucu bileşiklerin gideriminde biyosorpsiyon yöntemi yaygın olarak kullanılmaktadır. Bu çalışmada Bisfenol A'nı giderimi için Pinus resinosa kozalak tozu kullanılmıştır. Çalışmada, biyolojik materyaller sorbent olarak kullanılmıştır. Çalışmada, sıcaklık, pH, başlangıç BPA derişimi ve biyokütle derişiminin biyosorpsiyon üzerine etkisi incelenmiştir. Kozalak tozunun maksimum adsorpsiyon kapsitesi pH 5'de 0.155 mg/g olarak belirlenmiştir. Çam kozalağını maksimum BPA giderim verimi 30. dakikada, 60 0C de 65.5% olarak saptanmıştır. Çalışma, farklı sıcaklıklarda (40 0C, 50 0C, 60 0C), farklı BPA derişimlerinde (0.1ppm, 0.15ppm, 0.25ppm, and 0.5ppm) ve farklı biyokütle miktarları (0.3g, 0.2g, 0.1g and 0.05g) kullanılarak sürdürülmüştür. Çalışma bulguları, biyokütle miktarı arttıkça BPA giderim veriminin arttığını, ancak biyosorpsiyon kapasitesinin arttığını; 0.05 g biyokütle ile en yüksek biyosorpsiyon kapasitesi saptanmıştır.Deneysel verilerin Langmuir, Freundlich and Temkin izoerm modellerine uygunlukları araştırılmış, farklı sıcaklıklarda elde edilen verilerin Temkin izoterm modeline uyum gösterdiği, 40 0C de elde edilen verilerin Freundlich modeline de uyum gösterdiği ancak farklı sıcaklıklarda elde edilen verilerin Langmuir modeline uyum göstermediği sonucuna varılmıştır. Temkin izoterm modeli için 40 0C, 50 0C, 60 0C'de elde edilen R2 değerleri sırası ile 0.9233, 0.9804, and 0.999 olarak belirlenmiştir. BPA'nın biyosorpsiyonla giderim verimi ve lakkaz enzimi ile enzimatik giderim verimi karşılaştırılmıştır. Enzimatik BPA giderim çalışmaları pH 4 sodyum sitrat tamponu kullanılarak sürdürülmüş ve 0.1 ppm ve 0.5 ppm BPA için 30 dakikalık deney sonucu elde edilen veriler biyosorpsiyon verileri ile karşılaştırılmıştır. Anahtar Kelimeler: Pinus resinosa; Çam kozalağı; Bisfenol A; Biosorpsiyon.' | ||
| 650 | 0 | 0 | _aBiosorpsiyon |
| 650 | 0 | 0 | _aBiosorption |
| 650 | 0 | 0 | _aÇam kozalağı |
| 650 | 0 | 0 | _aPine cone |
| 700 | 0 |
_aSupervisor: Erkurt, Hatice _91656 |
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| 942 |
_2ddc _cTS |
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| 505 | 1 |
_g1 _tCHAPTER 1 |
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| 505 | 1 |
_g1 _tINTRODUCTION |
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| 505 | 1 |
_g1 _tEndocrine System |
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| 505 | 1 |
_g1 _tEndocrine Disruptive Compounds (EDCs) |
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| 505 | 1 |
_g3 _tHealth effect of EDCs |
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| 505 | 1 |
_g4 _tMode of exposure to EDCs |
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| 505 | 1 |
_g4 _tDescription of Some Environmental EDCs |
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| 505 | 1 |
_g5 _tEnvironmental Exposure and Health Implications |
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| 505 | 1 |
_g6 _tBisphenol A |
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| 505 | 1 |
_g8 _tCommon Uses of BPA |
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| 505 | 1 |
_g8 _tEnvironmental Fate of BPA |
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| 505 | 1 |
_g10 _tHealth effect of BPA |
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| 505 | 1 |
_g10 _tGovernment regulation and discrepancies on BPA |
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| 505 | 1 |
_g11 _tResearch Objective and Motivation |
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| 505 | 1 |
_g12 _tCHAPTER 2 |
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| 505 | 1 |
_g12 _tLITERATURE REVIEW |
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| 505 | 1 |
_g13 _tCones of Pinus resinosa(Pine Cones) |
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| 505 | 1 |
_g15 _tBiosorption |
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| 505 | 1 |
_g15 _tBisorbent |
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| 505 | 1 |
_g16 _tSource of Biomas for Biosorption |
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| 505 | 1 |
_g16 _tCharacteristics of Biosorbent |
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| 505 | 1 |
_g16 _tBisphenol A |
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| 505 | 1 |
_g17 _tEnzymatic Treament |
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| 505 | 1 |
_g17 _tENZYMES |
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| 505 | 1 |
_g21 _tCHAPTER 3 |
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| 505 | 1 |
_g21 _tANALYTICAL INSTRUMENTS |
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| 505 | 1 |
_g21 _tHigh Performance Liquid Chromatography (HPLC) |
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| 505 | 1 |
_g21 _tComponents of the HPLC Machine |
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| 505 | 1 |
_g22 _tHow the HPLC Operates |
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| 505 | 1 |
_g24 _tChromatographic view for BPA |
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| 505 | 1 |
_g26 _tConcentration Measurements |
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| 505 | 1 |
_g27 _tpH balance |
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| 505 | 1 |
_g27 _tOven |
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| 505 | 1 |
_g27 _tShaker |
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| 505 | 1 |
_g28 _tCentrifuge |
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| 505 | 1 |
_g29 _tMicro Filter |
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| 505 | 1 |
_g29 _tMATERIALS AND METHODS |
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| 505 | 1 |
_g29 _tMATERIALS |
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| 505 | 1 |
_g29 _tBisorbents Preparation |
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| 505 | 1 |
_g29 _tChemicals |
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| 505 | 1 |
_g30 _tMETHODS |
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| 505 | 1 |
_g30 _tEffects of pH |
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| 505 | 1 |
_g30 _tEffect of Temperature |
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| 505 | 1 |
_g30 _tEffects of Bio sorbent Dosage |
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| 505 | 1 |
_g31 _tAdsorption Isotherm |
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| 505 | 1 |
_g32 _tEnzymatic Study |
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| 505 | 1 |
_g32 _tCHAPTER 5 |
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| 505 | 1 |
_g34 _tRESULTS AND DISCUSSION |
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| 505 | 1 |
_g34 _tEffects of pH |
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| 505 | 1 |
_g36 _tEffects of Bio sorbent Dosage |
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| 505 | 1 |
_g45 _tEffect of Temperature |
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| 505 | 1 |
_g47 _tEffect of initial concentration on BPA Sorption |
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| 505 | 1 |
_g48 _tAdsorption Isotherm |
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| 505 | 1 |
_g52 _tPercentage removal of BPA by Laccase Enzymes |
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| 505 | 1 |
_g54 _tResult Comparison |
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| 505 | 1 |
_g56 _tCHAPTER 6 |
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| 505 | 1 |
_g56 _tCONCLUSIONS |
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| 505 | 1 |
_g57 _tREFERENCES |
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| 999 |
_c365 _d365 |
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